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HISTORY OF TITANIUM

About 0.6% of the earth's crust is made up of titanium, making titanium the fourth most abundant structural metal after aluminum, iron, and magnesium, adn the ninth most abundant mineral overall. Titanium ore mainly comprises of ilmenite (FeTiO3) and rutile (TiO2).

The element was initially discovered in 1791 by clergyman and amateur mineralogist Gregor, but it is 4 years later that this was confirmed by Klaproth, a German chemist, analyzed rutile from Hungary and identified an oxide of an unknown element that he named "titanium" after the Titans, a race of powerful deities linked to the earth, the wind, and the sea, that were later supplanted by the Olympians, in Greek mythology.

Isolating the metal from the titanium ore proved to be a challenge, requiring titanium tetrachloride (TiCl4) as an intermittent step. High purity titanium (ductile) was impeded by the strong tendency of this metal to react with atmospheric oxygen and nitrogen. Only well into the 20th century (1937-1940) did a commercially attractive process surfaced, making use of inert atmospheric gases, resulting in a product that resembles a metallic sponge, and thus called "titanium sponge." This is the "Kroll process" and is still in use today. Only 5% of the TiCl4 production is used to produce titanium metal - a large amount is used as an opaque white paint pigment and has replaced lead for that purpose, worlwide.

Production capacity of titanium sponge in metric tons
USA Japan UK USSR China Total
1979 20 800 16 200 2 200 39 000 1 800 80 000
1980 25 400 23 200 1 800 42 600 1 800 94 800
1982 27 600 27 300 1 400 44 400 2 300 103 000
1984 30 400 34 000 5 000 47 200 2 700 119 300
1987 25 400 23 100 5 000 49 900 2 700 106 100
1990 30 400 28 800 5 000 52 200 2 700 119 100